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以钛酸丁酯和硝酸钇为主要原料,采用溶胶-凝胶法制备了掺杂钇的纳米TiO2(Y-TiO2).用XRD、TEM等方法对其进行了表征,晶型为锐钛矿,粒径范围12~25 nm.以罗丹明B(RhB)为目标降解物,考察催化剂的光催化活性.结果显示,当Y3+的掺杂摩尔分数为0.5%,催化剂质量浓度为0.2 g/L,紫外光照80 min时,RhB的降解率可达98.2%,较纯TiO2光催化活性提高了160%.
Abstract:Nanosized Y-doped TiO2(Y-TiO2) was prepared using tetrabutyl titanate and yttrium nitrate as major raw materials by sol-gel process.The product was characterized by XRD and TEM.The results showed that the material was anatase and the particle size was in the range of 1225 nm.The photocatalytic activity of the catalyst was evaluated by method of catalytic degradation of Rhodamine-B(RhB).For the photodegradation of RhB,the optimal Y3+ dopant concentration is 0.5 % and the concentration of catalyst is 0.2 g/L.The degradation rate of RhB was 98.2 % under UV-light irradiation of 80 min,whose photocatalysic activity is increased 160 % higher than that of pure TiO2.
[1]Habibi M H,Tangestaninejad S,Yadollallahi B.Photo-catalytic mineralisation of mercaptans as environmental pol-lutants in aquatic system using TiO2 suspension[J].AppliedCatalysis B:Environ,2001,33(1):57-63.
[2]梅燕,贾振斌,曹江林,等.纳米TiO2粉体的固定及其对甲醇的光电复合氧化[J].太阳能学报,2002,23(2):199-202.
[3]Ollis D F,Al-Ekabi H.Photo-catalytic purification andtreatment of water and air[C].Elsevier:Amsterdam,1993.
[4]Choi W Y,Termin A,HoffmannM R,et al.The role ofmetal ion dopants in quantum-sized TiO2:correlation be-tween photoreactivity and charge carrier recombination dy-namics[J].Journal of Physical Chemistry,1994,98(51):13669-13679.
[5]Madhusudan R K,Baruwati B,Jayalakshmi M,et al.S-,N-and C-doped titanium dioxide nanoparticles synthesis,characterization and redox charge transfer study[J].Journalof Solid State Chemistry,2005,178(11):3352-3358.
[6]Bessekhouad Y,Robert D,Weber J V.Bi2S3/TiO2 and CdS/TiO2 degradation of organic pollutant[J].Journal of Photochemistry and Photobiology A:Chem-istry,2004,163(3):569-580.
[7]尹晓红,辛峰,张风宝,等.含磁性γ-Fe2O3核的TiO2/Al2O3催化剂的制备及光催化性能[J].精细化工,2006,23(1):58-61.
[8]苏碧桃,董娜,慕红梅,等.Fe3+-CdS/TiO2复合半导体光催化剂的制备与表征[J].精细化工,2007,24(9):856-859,898.
[9]Stylidi M,Kondarides D I,Verykios X E.Visible light-in-duced photocatalytic degradation of acid orange 7 in aqueousTiO2 suspensions[J].Applied Catalysis B:Environmental,2004,47(3):189-201.
[10]Sung-Suh H M,Choi J R,Hah H J,et al.Comparisonof Ag deposition effects on the photocatalytic activity ofnanoparticulate TiO2 under visible and UV light irradiation[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,163(1/2):37-44.
[11]李佑稷,宋智娟,李志平,等.活性炭负载Cu离子掺杂纳米TiO2颗粒的制备及光催化性能[J].高等学校化学学报,2007,28(9):1710-1715.
[12]苏碧桃,敏世雄,白洁,等.共轭高分子PF/TiO2纳米复合材料的合成与催化性能[J].精细化工,2006,23(9):837-840.
基本信息:
DOI:
中图分类号:O643.36
引用信息:
[1]丁欣宇,景晓辉,施磊等.掺杂钇的纳米TiO_2的制备及光催化性能研究[J].南通大学学报(自然科学版),2008,No.25(02):44-46+72.
基金信息:
江苏省高校自然科学计划项目(06KJD530153);; 南通市应用研究计划项目(K2006017)