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在全球能源需求不断增长与可持续发展要求日益突出的背景下，摩擦纳米发电机（TENG）因其低成本、结构简洁及对低频机械能的高效收集能力而备受关注。其中，含氟聚合物凭借优异的电负性、低表面能、化学惰性及稳定的介电性能，成为制备高性能TENG摩擦层的关键材料。本文系统综述了近年来含氟聚合物基TENG的研究进展。首先，介绍了静电纺丝、熔融注塑、表面喷涂及3D打印等多种摩擦层加工方式，并对各方法的优势与局限进行了对比分析。随后，重点探讨了通过表面处理、结构改性、功能填料引入及材料复合等策略提升输出性能的研究成果，阐明了含氟聚合物在提升电荷密度、能量转换效率与长期稳定性方面的独特作用。在此基础上，总结了当前研究所面临的主要挑战，如规模化制备难度、环境适应性不足以及器件耐久性与可集成性问题，并展望了未来在新型含氟材料设计、多功能一体化结构及可穿戴能源系统应用中的发展方向。本文旨在为含氟聚合物基TENG的材料优化与应用拓展提供参考，为推动绿色可持续能源技术发展提供新思路。
Abstract：With the growing global demand for energy and the urgent need for sustainable development， triboelectric nanogenerators (TENGs) have attracted significant attention due to their low cost， simple structure， and high efficiency in harvesting low-frequency mechanical energy. Among the various candidate materials， fluoropolymers have emerged as key components for fabricating high-performance triboelectric layers， owing to their strong electronegativity， low surface energy， chemical inertness， and stable dielectric properties. This review provides a comprehensive summary of recent progress in fluoropolymer-based TENGs. First， various fabrication methods for triboelectric layers， including electrospinning， melt injection molding， surface spraying， and 3D printing， are introduced and comparatively analyzed in terms of their advantages and limitations. Next， strategies for enhancing output performance—such as surface treatment， structural modification， functional filler incorporation， and material hybridization—are highlighted， demonstrating the unique role of fluoropolymers in improving charge density， energy conversion efficiency， and long-term stability. Furthermore， the current challenges in this field， including difficulties in large-scale fabrication， insufficient environmental adaptability， and issues of durability and device integration， are discussed. Finally， the future development directions are outlined， focusing on the design of novel fluorinated materials， multifunctional integrated structures， and wearable energy systems. This review aims to provide insights into the optimization and application of fluoropolymer-based TENGs， contributing to the advancement of green and sustainable energy technologies.
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基本信息:
中图分类号:TM31
引用信息:
[1]段意洋,王萍,张岩.含氟聚合物在摩擦电能量收集中的应用进展[J].南通大学学报(自然科学版)().
基金信息:
江苏省高等学校自然科学研究重大项目（22KJA540002）
2026-06-04
2026-06-04
2026-06-04